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Effect of P5+/Al3+ molar ratio on structure and spectroscopic properties of Nd3+/Al3+/P5+ co-doped silica glass
Xu, Wenbin; Wang, Meng; Zhang, Lei; Shao, Chongyun; Chen, Danping; Wang, Shikai; Yu, Chunlei; Hu, Lili; woshiwsk@163.com; sdycllcy@163.com; hulili@siom.ac.cn
2016
发表期刊J. Non-Cryst. Solids
卷号432页码:285
摘要Glasses with compositions of (95.8-x) SiO2-4Al(2)O(3)-xP(2)O(5)-0.2Nd(2)O(3) (in mol%, x = 0-10) were prepared. Structural variation caused by P5+ was investigated by Judd-Ofelt parameters and Raman spectra. Results reveal that Nd3+ preferentially coordinates to P=O sites at molar ratio of P5+/Al3+ > 1 and thus it leads to a sudden change in fluorescence effective linewidth, stimulated emission cross section, fluorescence lifetime and non-radiative transition rate of Nd3+ ions. The fluorescence lifetime changes in the range of 315-379 mu s. The emission cross section changes in the range of 139-1.79 x 10(-20) cm(2). With the increase of P5+/Al3+ ratio, the fluorescence effective linewidth varies from 45.77 to 37.03 nm. The shortest fluorescence lifetime was observed at molar ratio of P5+/Al3+ = 1. The maximum non-radiative transition rate of 1694/s occurred at molar ratio of P5+/Al3+ = 1.25. The highest emission cross section of 1.79 x 10(-20) cm(2) was obtained at the highest P5+/Al3+ molar ratio. Furthermore, structure-property relationship in these glasses was discussed through Judd-Ofelt parameters and luminescent behaviors. (C) 2015 Elsevier B.V. All rights reserved.
文章类型Article
部门归属单元
DOI10.1016/j.jnoncrysol.2015.10.027
资助者National Natural Science Foundation of China [61505232] ; National Natural Science Foundation of China [61505232] ; National Natural Science Foundation of China [61505232] ; National Natural Science Foundation of China [61505232]
收录类别SCI
资助者National Natural Science Foundation of China [61505232] ; National Natural Science Foundation of China [61505232] ; National Natural Science Foundation of China [61505232] ; National Natural Science Foundation of China [61505232]
WOS记录号WOS:000367769300016
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文献类型期刊论文
条目标识符http://ir.siom.ac.cn/handle/181231/28278
专题高功率激光单元技术研发中心
通讯作者woshiwsk@163.com; sdycllcy@163.com; hulili@siom.ac.cn
作者单位中国科学院上海光学精密机械研究所
推荐引用方式
GB/T 7714
Xu, Wenbin,Wang, Meng,Zhang, Lei,et al. Effect of P5+/Al3+ molar ratio on structure and spectroscopic properties of Nd3+/Al3+/P5+ co-doped silica glass[J]. J. Non-Cryst. Solids,2016,432:285.
APA Xu, Wenbin.,Wang, Meng.,Zhang, Lei.,Shao, Chongyun.,Chen, Danping.,...&hulili@siom.ac.cn.(2016).Effect of P5+/Al3+ molar ratio on structure and spectroscopic properties of Nd3+/Al3+/P5+ co-doped silica glass.J. Non-Cryst. Solids,432,285.
MLA Xu, Wenbin,et al."Effect of P5+/Al3+ molar ratio on structure and spectroscopic properties of Nd3+/Al3+/P5+ co-doped silica glass".J. Non-Cryst. Solids 432(2016):285.
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