KMS Shanghai Institute of Optics and Fine Mechanics, CAS
Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration | |
He, Jin; Ma, Pengfei; Zhang, Ge; Li, Rihong; Zhang, Long; lirihong@siom.ac.cn; lzhang@siom.ac.cn | |
2016 | |
Source Publication | RSC Adv.
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Volume | 6Issue:101Pages:99149 |
Abstract | Mesoporous phosphate materials with chemical diversity and a high surface area are essential for their practical applications as heavy metal ion adsorbent materials. Herein, novel gallium aluminum phosphate mesoporous glasses are prepared through a simple aqueous sol-gel route free of any surfactant or template. The glass structure and its evolution from the gel to the final glass were monitored using solid-state NMR techniques, providing detailed insight into the reaction mechanism. During the formation of the mesoporous GaAlPO4 glass, the gallium entered into the PO4 tetrahedron via Ga-O-P bonds. The resulting mesoporous glass samples were tested as adsorbents to remove Pb(II) anions from solution and the ternary oxide glasses show high adsorption capacities (>36.63 mg g(-1), that is 0.18 mmol g(-1)). Owing to their integrated features (including their variable compositions, high specific surface area, tunable pore size and shape flexibility) as well as specific acid-base surface properties, such mesoporous gallium aluminum phosphate materials are also expected to have potential either as catalysts or catalyst supports for industrial applications. |
Subtype | Article |
Department | 材料 |
DOI | 10.1039/c6ra17766b |
Funding Organization | National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] |
Indexed By | SCI |
Funding Organization | National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] |
WOS ID | WOS:000387427800071 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.siom.ac.cn/handle/181231/28176 |
Collection | 中科院强激光材料重点实验室 |
Corresponding Author | lirihong@siom.ac.cn; lzhang@siom.ac.cn |
Affiliation | 中国科学院上海光学精密机械研究所 |
Recommended Citation GB/T 7714 | He, Jin,Ma, Pengfei,Zhang, Ge,et al. Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration[J]. RSC Adv.,2016,6(101):99149. |
APA | He, Jin.,Ma, Pengfei.,Zhang, Ge.,Li, Rihong.,Zhang, Long.,...&lzhang@siom.ac.cn.(2016).Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration.RSC Adv.,6(101),99149. |
MLA | He, Jin,et al."Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration".RSC Adv. 6.101(2016):99149. |
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