KMS Shanghai Institute of Optics and Fine Mechanics, CAS
| Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration | |
| He, Jin; Ma, Pengfei; Zhang, Ge; Li, Rihong; Zhang, Long; lirihong@siom.ac.cn; lzhang@siom.ac.cn | |
| 2016 | |
| Source Publication | RSC Adv.
 |
| Volume | 6Issue:101Pages:99149 |
| Abstract | Mesoporous phosphate materials with chemical diversity and a high surface area are essential for their practical applications as heavy metal ion adsorbent materials. Herein, novel gallium aluminum phosphate mesoporous glasses are prepared through a simple aqueous sol-gel route free of any surfactant or template. The glass structure and its evolution from the gel to the final glass were monitored using solid-state NMR techniques, providing detailed insight into the reaction mechanism. During the formation of the mesoporous GaAlPO4 glass, the gallium entered into the PO4 tetrahedron via Ga-O-P bonds. The resulting mesoporous glass samples were tested as adsorbents to remove Pb(II) anions from solution and the ternary oxide glasses show high adsorption capacities (>36.63 mg g(-1), that is 0.18 mmol g(-1)). Owing to their integrated features (including their variable compositions, high specific surface area, tunable pore size and shape flexibility) as well as specific acid-base surface properties, such mesoporous gallium aluminum phosphate materials are also expected to have potential either as catalysts or catalyst supports for industrial applications. |
| Subtype | Article |
| Department | 材料 |
| DOI | 10.1039/c6ra17766b |
| Funding Organization | National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] |
| Indexed By | SCI |
| Funding Organization | National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] ; National Natural Science Foundation of China [61275208] |
| WOS ID | WOS:000387427800071 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.siom.ac.cn/handle/181231/28176 |
| Collection | 中科院强激光材料重点实验室 |
| Corresponding Author | lirihong@siom.ac.cn; lzhang@siom.ac.cn |
| Affiliation | 中国科学院上海光学精密机械研究所 |
| Recommended Citation GB/T 7714 | He, Jin,Ma, Pengfei,Zhang, Ge,et al. Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration[J]. RSC Adv.,2016,6(101):99149. |
| APA | He, Jin.,Ma, Pengfei.,Zhang, Ge.,Li, Rihong.,Zhang, Long.,...&lzhang@siom.ac.cn.(2016).Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration.RSC Adv.,6(101),99149. |
| MLA | He, Jin,et al."Sol-gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration".RSC Adv. 6.101(2016):99149. |
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