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Monodisperse beta-NaYF4:Yb3+, Tm3+ hexagonal microplates with efficient NIR-to-NIR up-conversion emission developed via ion exchange
Fan, Shaohua; Gao, Guojun; Busko, Dmitry; Lin, Zhiquan; Wang, Shikai; Wang, Xue; Sun, Shiyu; Turshatov, Andrey; Richards, Bryce S.; Sun, Hongtao; Hu, Lili; guojun.gao@kit.edu; hulili@siom.ac.cn
2017
Source PublicationJ. Mater. Chem. C
Volume5Issue:37Pages:9770
AbstractMonodisperse beta-NaYF4:Yb3+, Tm3+ (NYF) hexagonal microplates with efficient near-infrared (NIR)-to-NIR up-conversion (UC) developed via a new ion-exchange modified hydrothermal method are reported. Ion exchange modification (IEM) not only significantly increases the UC intensity by up to 1000 times and prolongs the emission lifetimes of Tm3+ and Yb3+, but also enables the monodisperse morphology and size of hexagonal microplates to be maintained. A high UC quantum efficiency (QE) of 3.1% is obtained for IEM beta-NaYF4: 20%Yb3+, 1%Tm3+ when excited with 980 nm light at a power density of 10W cm(-2). The UC emission properties can be finely tailored by changing the NaF/NYF molar ratio (NYF represents lanthanide doped beta-NaYF4) and the doping concentration of Tm3+. The two photon NIR UC emission centered at B803 nm (arising from Tm3+:3H(4)-3H(6)) dominates the UC emission spectrum and high concentrations of Tm3+ favor NIR UC further. A proof-of-concept optical image of printed patterns is demonstrated to verify their applications in security. These results suggest the promising applications of the newly developed monodisperse beta-NaYF4:Yb3+, Tm3+ hexagonal microplates in security, luminescent labels, solid-state lasers, amplifiers, and biomedicine.
SubtypeArticle
Department材料
DOI10.1039/c7tc03373g
Funding OrganizationChina: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN) ; China: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN) ; China: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN) ; China: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN)
Indexed BySCI
Funding OrganizationChina: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN) ; China: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN) ; China: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN) ; China: National Natural Science Foundation of China [61405215, 61505232]; Germany: Helmholtz Association's research program Science and Technology of Nanosystems (STN)
WOS IDWOS:000412069100030
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.siom.ac.cn/handle/181231/28132
Collection中科院强激光材料重点实验室
Corresponding Authorguojun.gao@kit.edu; hulili@siom.ac.cn
Affiliation中国科学院上海光学精密机械研究所
Recommended Citation
GB/T 7714
Fan, Shaohua,Gao, Guojun,Busko, Dmitry,et al. Monodisperse beta-NaYF4:Yb3+, Tm3+ hexagonal microplates with efficient NIR-to-NIR up-conversion emission developed via ion exchange[J]. J. Mater. Chem. C,2017,5(37):9770.
APA Fan, Shaohua.,Gao, Guojun.,Busko, Dmitry.,Lin, Zhiquan.,Wang, Shikai.,...&hulili@siom.ac.cn.(2017).Monodisperse beta-NaYF4:Yb3+, Tm3+ hexagonal microplates with efficient NIR-to-NIR up-conversion emission developed via ion exchange.J. Mater. Chem. C,5(37),9770.
MLA Fan, Shaohua,et al."Monodisperse beta-NaYF4:Yb3+, Tm3+ hexagonal microplates with efficient NIR-to-NIR up-conversion emission developed via ion exchange".J. Mater. Chem. C 5.37(2017):9770.
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