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Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na4MB2P3O13 (M = Rb, Cs) exhibiting a second-harmonic generation response
Wu, Chao; Li, Longhua; Yang, Gang; Song, Junling; Yan, Bing; Humphrey, Mark G.; Zhang, Long; Shao, Jianda; Zhang, Chi; czhang@siom.ac.cn; chizhang@tongji.edu.cn
2017
发表期刊Dalton Trans.
卷号46期号:37页码:12605
摘要The first non-centrosymmetric mixed-alkali-metal borophosphates, Na4MB2P3O13 (M = Rb 1, Cs 2), were obtained using a low-temperature flux method. Single-crystal X-ray diffraction studies of 1 and 2 reveal that the two compounds are isostructural, both crystallizing in the orthorhombic space group Pna2(1); their structures consist of novel 1D borophosphate chains constructed from B2P3O14 fundamental building units, assembled into a 3D framework by alkali metal cations. Second-harmonic generation (SHG) measurements show that 1 and 2 are type-I phase-matchable, with SHG responses ca. 0.35 and 0.42 times that of KH2PO4, respectively. The cut-off edges of 1 and 2 are ca. 276 and 267 nm, respectively, which suggests that they are potential ultraviolet nonlinear optical materials. Density functional theory calculations were employed to shed light on the band structure and density of states as well as the electron density distribution.
文章类型Article
部门归属材料
DOI10.1039/c7dt02649h
资助者National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council
收录类别SCI
资助者National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs for 111 Project [B13025]; Australian Research Council
WOS记录号WOS:000411702300027
引用统计
文献类型期刊论文
条目标识符http://ir.siom.ac.cn/handle/181231/28127
专题中科院强激光材料重点实验室
通讯作者czhang@siom.ac.cn; chizhang@tongji.edu.cn
作者单位中国科学院上海光学精密机械研究所
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GB/T 7714
Wu, Chao,Li, Longhua,Yang, Gang,et al. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na4MB2P3O13 (M = Rb, Cs) exhibiting a second-harmonic generation response[J]. Dalton Trans.,2017,46(37):12605.
APA Wu, Chao.,Li, Longhua.,Yang, Gang.,Song, Junling.,Yan, Bing.,...&chizhang@tongji.edu.cn.(2017).Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na4MB2P3O13 (M = Rb, Cs) exhibiting a second-harmonic generation response.Dalton Trans.,46(37),12605.
MLA Wu, Chao,et al."Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na4MB2P3O13 (M = Rb, Cs) exhibiting a second-harmonic generation response".Dalton Trans. 46.37(2017):12605.
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