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Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet
Wu, Chao; Li, Longhua; Song, Junling; Yang, Gang; Humphrey, Mark G.; Zhang, Chi; chizhang@tongji.edu.cn
2017
发表期刊Inorg. Chem.
卷号56期号:3页码:1340
摘要Two novel noncentrosymmetric metal borates, Ba-2[B4O7(OH)(2)] (1) and Na[B5O7(OH)(2)](H2O) (2), have been obtained by hydrothermal and surfactant-thermal means. Compound 1 consists of novel one-dimensional borate chains formed by B3O9 and B3O8 rings, assembled into a three-dimensional (3D) framework by Ba2+ cations. The structure of 2 exhibits double-helical chains constructed from B5O10 primary building units, which are interconnected via Na+ cations and H-bonding interactions to generate a 3D framework. Second-harmonic-generation (SHG) measurements show that 1 shows a phase-matching powder SHG response of similar to 2.2 x KH2PO4 (KDP), while 2 exhibits a weak SHG response. The cutoff edges of 1 and 2 are similar to 242 and similar to 221 nm, respectively, which suggests that they are potential ultraviolet nonlinear optical (NLO) materials. Band structures and NLO properties have also been theoretically studied.
文章类型Article
部门归属材料
DOI10.1021/acs.inorgchem.6b02457
资助者National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council
收录类别SCI
资助者National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council
WOS记录号WOS:000393630300039
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.siom.ac.cn/handle/181231/28078
专题中科院强激光材料重点实验室
通讯作者chizhang@tongji.edu.cn
作者单位中国科学院上海光学精密机械研究所
推荐引用方式
GB/T 7714
Wu, Chao,Li, Longhua,Song, Junling,et al. Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet[J]. Inorg. Chem.,2017,56(3):1340.
APA Wu, Chao.,Li, Longhua.,Song, Junling.,Yang, Gang.,Humphrey, Mark G..,...&chizhang@tongji.edu.cn.(2017).Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet.Inorg. Chem.,56(3),1340.
MLA Wu, Chao,et al."Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet".Inorg. Chem. 56.3(2017):1340.
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