SIOM OpenIR  > 中科院强激光材料重点实验室
Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet
Wu, Chao; Li, Longhua; Song, Junling; Yang, Gang; Humphrey, Mark G.; Zhang, Chi; chizhang@tongji.edu.cn
2017
Source PublicationInorg. Chem.
Volume56Issue:3Pages:1340
AbstractTwo novel noncentrosymmetric metal borates, Ba-2[B4O7(OH)(2)] (1) and Na[B5O7(OH)(2)](H2O) (2), have been obtained by hydrothermal and surfactant-thermal means. Compound 1 consists of novel one-dimensional borate chains formed by B3O9 and B3O8 rings, assembled into a three-dimensional (3D) framework by Ba2+ cations. The structure of 2 exhibits double-helical chains constructed from B5O10 primary building units, which are interconnected via Na+ cations and H-bonding interactions to generate a 3D framework. Second-harmonic-generation (SHG) measurements show that 1 shows a phase-matching powder SHG response of similar to 2.2 x KH2PO4 (KDP), while 2 exhibits a weak SHG response. The cutoff edges of 1 and 2 are similar to 242 and similar to 221 nm, respectively, which suggests that they are potential ultraviolet nonlinear optical (NLO) materials. Band structures and NLO properties have also been theoretically studied.
SubtypeArticle
Department材料
DOI10.1021/acs.inorgchem.6b02457
Funding OrganizationNational Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council
Indexed BySCI
Funding OrganizationNational Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council
WOS IDWOS:000393630300039
Citation statistics
Document Type期刊论文
Identifierhttp://ir.siom.ac.cn/handle/181231/28078
Collection中科院强激光材料重点实验室
Corresponding Authorchizhang@tongji.edu.cn
Affiliation中国科学院上海光学精密机械研究所
Recommended Citation
GB/T 7714
Wu, Chao,Li, Longhua,Song, Junling,et al. Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet[J]. Inorg. Chem.,2017,56(3):1340.
APA Wu, Chao.,Li, Longhua.,Song, Junling.,Yang, Gang.,Humphrey, Mark G..,...&chizhang@tongji.edu.cn.(2017).Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet.Inorg. Chem.,56(3),1340.
MLA Wu, Chao,et al."Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet".Inorg. Chem. 56.3(2017):1340.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wu, Chao]'s Articles
[Li, Longhua]'s Articles
[Song, Junling]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wu, Chao]'s Articles
[Li, Longhua]'s Articles
[Song, Junling]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wu, Chao]'s Articles
[Li, Longhua]'s Articles
[Song, Junling]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.