Covalent Modification of MoS2 with Poly(N-vinylcarbazole) for Solid-State Broadband Optical Limiters

doi:10.1002/chem.201505017

	Covalent Modification of MoS2 with Poly(N-vinylcarbazole) for Solid-State Broadband Optical Limiters
	Cheng, Hongxia; Dong, Ningning; Bai, Ting; Song, Yi; Wang, Jun; Qin, Yuanhao; Zhang, Bin; Chen, Yu; jwang@siom.ac.cn; chentangyu@yahoo.com
	2016
发表期刊	Chem.-Eur. J.
卷号	22 期号:13 页码:4500
摘要	New soluble MoS2 nanosheets covalently functionalized with poly(N-vinylcarbazole) (MoS2-PVK) were in situ synthesized for the first time. In contrast to MoS2 and MoS2/PVK blends, both the solution of MoS2-PVK in DMF and MoS2-PVK/poly(methyl methacrylate) (PMMA) film show superior nonlinear optical and optical limiting responses. The MoS2-PVK/PMMA film shows the largest nonlinear coefficients ((eff)) of about 917cmGW(-1) at =532nm (cf. 100.69cmGW(-1) for MoS2/PMMA and 125.12cmGW(-1) for MoS2/PVK/PMMA) and about 461cmGW(-1) at =1064nm (cf. -48.92cmGW(-1) for MoS2/PMMA and 147.56cmGW(-1) for MoS2/PVK/PMMA). A larger optical limiting effect, with thresholds of about 0.3GWcm(-2) at =532nm and about 0.5GWcm(-2) at =1064nm, was also achieved from the MoS2-PVK/PMMA film. These values are among the highest reported for MoS2-based nonlinear optical materials. These results show that covalent functionalization of MoS2 with polymers is an effective way to improve nonlinear optical responses for efficient optical limiting devices.
文章类型	Article
部门归属	材料
DOI	10.1002/chem.201505017
资助者	National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000 ; National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000 ; National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000 ; National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000
收录类别	SCI
资助者	National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000 ; National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000 ; National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000 ; National Natural Science Foundation of China [61378072, 61178007, 61522510, 61308087]; Ministry of Education and State Administration of Foreign Experts Affairs [TS2010HDLG024]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; National 10000
WOS记录号	WOS:000372808100030
引用统计	被引频次：15[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.siom.ac.cn/handle/181231/28040
专题	中科院强激光材料重点实验室
通讯作者	jwang@siom.ac.cn; chentangyu@yahoo.com
作者单位	中国科学院上海光学精密机械研究所
推荐引用方式 GB/T 7714	Cheng, Hongxia,Dong, Ningning,Bai, Ting,et al. Covalent Modification of MoS2 with Poly(N-vinylcarbazole) for Solid-State Broadband Optical Limiters[J]. Chem.-Eur. J.,2016,22(13):4500.
APA	Cheng, Hongxia.,Dong, Ningning.,Bai, Ting.,Song, Yi.,Wang, Jun.,...&chentangyu@yahoo.com.(2016).Covalent Modification of MoS2 with Poly(N-vinylcarbazole) for Solid-State Broadband Optical Limiters.Chem.-Eur. J.,22(13),4500.
MLA	Cheng, Hongxia,et al."Covalent Modification of MoS2 with Poly(N-vinylcarbazole) for Solid-State Broadband Optical Limiters".Chem.-Eur. J. 22.13(2016):4500.