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Covalent functionalization of reduced graphene oxide with porphyrin by means of diazonium chemistry for nonlinear optical performance
Wang, Aijian; Yu, Wang; Huang, Zhipeng; Zhou, Feng; Song, Jingbao; Song, Yinglin; Long, Lingliang; Cifuentes, Marie P.; Humphrey, Mark G.; Zhang, Long; Shao, Jianda; Zhang, Chi; chizhang@tongji.edu.cn
2016
发表期刊Sci Rep
卷号6
摘要Reduced graphene oxide (RGO)-porphyrin (TPP) nanohybrids (RGO-TPP 1 and RGO-TPP 2) were prepared by two synthetic routes that involve functionalization of the RGO using diazonium salts. The microscopic structures, morphology, photophysical properties and nonlinear optical performance of the resultant RGO-TPP nanohybrids were investigated. The covalent bonding of the porphyrin-functionalized-RGO nanohybrid materials was confirmed by Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, and thermogravimetric analysis. Attachment of the porphyrin units to the surface of the RGO by diazotization significantly improves the solubility and ease of processing of these RGO-based nanohybrid materials. Ultraviolet/visible absorption and steady-state fluorescence studies indicate considerable p-p interactions and effective photo-induced electron and/or energy transfer between the porphyrin moieties and the extended p-system of RGO. The nonlinear optical properties of RGO-TPP 1 and RGO-TPP 2 were investigated by open-aperture Z-scan measurements at 532 nm with both 4 ns and 21 ps laser pulses, the results showing that the chemical nanohybrids exhibit improved nonlinear optical properties compared to those of the benchmark material C-60, and the constituent RGO or porphyrins.
文章类型Article
部门归属材料
DOI10.1038/srep23325
资助者National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T
收录类别SCI
资助者National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T ; National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China for the International Science Linkages Program [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research T
WOS记录号WOS:000372695600001
引用统计
文献类型期刊论文
条目标识符http://ir.siom.ac.cn/handle/181231/28039
专题中科院强激光材料重点实验室
通讯作者chizhang@tongji.edu.cn
作者单位中国科学院上海光学精密机械研究所
推荐引用方式
GB/T 7714
Wang, Aijian,Yu, Wang,Huang, Zhipeng,et al. Covalent functionalization of reduced graphene oxide with porphyrin by means of diazonium chemistry for nonlinear optical performance[J]. Sci Rep,2016,6.
APA Wang, Aijian.,Yu, Wang.,Huang, Zhipeng.,Zhou, Feng.,Song, Jingbao.,...&chizhang@tongji.edu.cn.(2016).Covalent functionalization of reduced graphene oxide with porphyrin by means of diazonium chemistry for nonlinear optical performance.Sci Rep,6.
MLA Wang, Aijian,et al."Covalent functionalization of reduced graphene oxide with porphyrin by means of diazonium chemistry for nonlinear optical performance".Sci Rep 6(2016).
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