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Covalent functionalization of graphene oxide with porphyrin and porphyrin incorporated polymers for optical limiting
Du, Yinlong; Dong, Ningning; Zhang, Menghan; Zhu, Kai; Na, Ruiqi; Zhang, Shuling; Sun, Ningwei; Wang, Guibin; Wang, Jun; wgb@jlu.edu.cn; jwang@siom.ac.cn
2017
发表期刊Phys. Chem. Chem. Phys.
卷号19期号:3页码:2252
摘要Porphyrin-graphene composites have attracted increasing attention due to a number of intriguing functions, and their photoelectrical and catalytic performances are expected to be modulated through different approaches. In the present study, a designed polymer based on phenyl sulfone, (p-amino)phenylhydroquinone, and a symmetrical dinaphthylporphyrin were covalently attached to a graphene oxide (GO) sheet. The formation of the nanohybrid was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and Raman, ultraviolet-visible (UV-vis) absorption, steady and transient fluorescence spectroscopy techniques. The nonlinear optical and optical limiting performances of the hybrid were investigated using Z-scan measurements at 532 nm and 1064 nm. For comparison, a porphyrin functionalized GO hybrid was synthesized as a reference. At the same linear transmittance, the polymer functionalized GO exhibited a stronger optical limiting response and a larger nonlinear extinction coefficient than the individual GO, porphyrinated polymer, and porphyrin functionalized GO hybrid analogue, and its intrinsic photophysical mechanism was discussed in detail. More importantly, further improvement of its nonlinear optical properties can be achieved by the chemical reduction of the hybrid. The enhanced nonlinear optical performance originated from the effective combination of nonlinear scattering, reverse saturable absorption, and a possible photo-induced electron/energy transfer mechanism from donor porphyrin moieties in the polymer backbone to acceptor graphene. Our result might provide a new avenue for the development of graphene-porphyrin materials in the field of photocatalysis, nonlinear optics, and optoelectronic devices.
文章类型Article
部门归属材料
DOI10.1039/c6cp05920a
资助者PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189] ; PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189] ; PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189] ; PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189]
收录类别SCI
资助者PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189] ; PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189] ; PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189] ; PhD Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Program of BIC, CAS [181231KYSB20130007]; Strategic Priority Research Program of CAS [XDB160307]; China Scholarship Council (CSC) [201606170189]
WOS记录号WOS:000394426400063
引用统计
文献类型期刊论文
条目标识符http://ir.siom.ac.cn/handle/181231/28038
专题中科院强激光材料重点实验室
通讯作者wgb@jlu.edu.cn; jwang@siom.ac.cn
作者单位中国科学院上海光学精密机械研究所
推荐引用方式
GB/T 7714
Du, Yinlong,Dong, Ningning,Zhang, Menghan,et al. Covalent functionalization of graphene oxide with porphyrin and porphyrin incorporated polymers for optical limiting[J]. Phys. Chem. Chem. Phys.,2017,19(3):2252.
APA Du, Yinlong.,Dong, Ningning.,Zhang, Menghan.,Zhu, Kai.,Na, Ruiqi.,...&jwang@siom.ac.cn.(2017).Covalent functionalization of graphene oxide with porphyrin and porphyrin incorporated polymers for optical limiting.Phys. Chem. Chem. Phys.,19(3),2252.
MLA Du, Yinlong,et al."Covalent functionalization of graphene oxide with porphyrin and porphyrin incorporated polymers for optical limiting".Phys. Chem. Chem. Phys. 19.3(2017):2252.
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