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Charge state and energy transfer investigation of iron-chromium co-doped ZnS polycrystalline prepared by step-temperature diffusion for mid-infrared laser applications
Wang, XiangYong; Chen, Zhe; Zhang, Lianhan; Xu, Min; Chen, Guangzhu; Jiang, Benxue; Ke, Changjun; Zhang, Long; Hang, Yin; yhang@siom.ac.cn
2017
Source PublicationJ. Alloy. Compd.
Volume695Pages:3767
AbstractThe spectroscopic characterization and energy transfer mechanism of iron-chromium co-doped ZnS polycrystalline (Cr,Fe:ZnS) were reported with dimension of 10 mm x 10 mm x 1.5 mm produced by step-temperature thermal diffusion method. The infrared absorption is characterized by two absorption broad-bands centered at 1.67 mu m and 2.9 mu m which can be attributed to the spin-allowed transition T-5(2) <-> E-5 within the 3 d(4) shell of Cr2+ and Fe2+ ions. The valences of iron and chromium in ZnS were analyzed by X-ray photoelectron spectroscopy. Photoluminescence spectrum shows a relatively strong broad emission band centered at 4 mu m with a width of 800 nm (FWHM) under 1.56 mu m excitation at room temperature and reveals an effective Cr2+ -> Fe2+ energy transfer process. The measured photoluminescence decay was about 5 mu s at room temperature. All the results indicate that Cr, Fe: ZnS could be used as the gain medium operating at 3.5-4.5 mu m via Cr2+ -> Fe2+ energy transfer using a more convenient laser pump source in the near IR region. (C) 2016 Elsevier B.V. All rights reserved.
SubtypeArticle
Department材料
DOI10.1016/j.jallcom.2016.11.145
Funding OrganizationNational Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900] ; National Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900] ; National Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900] ; National Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900]
Indexed BySCI
Funding OrganizationNational Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900] ; National Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900] ; National Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900] ; National Nature Science Founds of China [51502321, 61405221, 61575198, 61378069]; Shanghai City Star Program [14QB1400900]
WOS IDWOS:000391818100102
Citation statistics
Document Type期刊论文
Identifierhttp://ir.siom.ac.cn/handle/181231/28031
Collection中科院强激光材料重点实验室
Corresponding Authoryhang@siom.ac.cn
Affiliation中国科学院上海光学精密机械研究所
Recommended Citation
GB/T 7714
Wang, XiangYong,Chen, Zhe,Zhang, Lianhan,et al. Charge state and energy transfer investigation of iron-chromium co-doped ZnS polycrystalline prepared by step-temperature diffusion for mid-infrared laser applications[J]. J. Alloy. Compd.,2017,695:3767.
APA Wang, XiangYong.,Chen, Zhe.,Zhang, Lianhan.,Xu, Min.,Chen, Guangzhu.,...&yhang@siom.ac.cn.(2017).Charge state and energy transfer investigation of iron-chromium co-doped ZnS polycrystalline prepared by step-temperature diffusion for mid-infrared laser applications.J. Alloy. Compd.,695,3767.
MLA Wang, XiangYong,et al."Charge state and energy transfer investigation of iron-chromium co-doped ZnS polycrystalline prepared by step-temperature diffusion for mid-infrared laser applications".J. Alloy. Compd. 695(2017):3767.
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