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MF2(M=Mg,Ca,Zn,Sr,Ba)对掺Yb^3+磷酸盐玻璃性质的影响
Alternative TitleInfluence of MF2(M = Mg, Ca, Zn, Sr, Ba) on properties of Yb3+-doped phosphate glasses
戴世勋; 杨建虎; 戴能利; 胡丽丽; 姜中宏; Dai, SX (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
2003
Source Publication无机材料学报
Volume18Issue:3Pages:540
Abstract熔制了60P2O5·6A12O3·(33-x)Ba0.xBaF2·1Yb2O3(x=0,3,6,9)和60P2O5·6A12O3·27Ba0.6MF2·1Yb203(Af=Mg、Ca、Sr、zn、Ba)(分子分数)玻璃,测试了其折射率、密度、转变温度、析晶温度、熔点温度、红外光谱和紫外吸收光谱,讨论了二价氟化物MF2(M=Mg、Ca、Sr、Zn、Ba)对磷酸盐玻璃热稳定性及内部结构的影响,测试了Yb3+离子的吸收光谱、荧光光谱、荧光寿命,计算了光谱参数,讨论了MF2对Yb3+磷酸盐玻璃光谱性质的影响.结果
SubtypeArticle
Other Abstract60P(2)O(5).6Al(2)O(3).(33-x)BaO.xBaF(2).1Yb(2)O(3)(x=0,3,6,9) and 60P(2)O(5).6Al(2)O(3).27BaO. 6MF(2).1Yb(2)O(3)(M=Mg, Ca, Zn, Sr, Ba) glasses were prepared. The influence of bivalent fluoride MF2(M=Mg, Ca, Zn, Sr, Ba) on physical properties (such as refractive index, infrared spectra, density etc.) and thermal stability of phosphate glasses were investigated, as well as influence on glass structure through analysis of their UV and IR spectra. In addition, the absorption and fluorescent properties of Yb3+ ions were measured. The optical parameters (such as integrated absorption cross section and stimulated emission cross section, radiative lifetime etc.) of Yb3+ ions in samples were calculated. The effect of bivalent fluoride MF2(M=Mg, Ca, Zn, Sr, Ba) on the integrated absorption cross section and stimulated emission cross section of ytterbium phosphate glasses were discussed. The results obtained show that [PO4] network structure does not change significantly when bivalent fluorides are introduced as glass modifiers into phosphate glasses, while emission cross section, spontaneous emission probabilities and TWHM (Fluorescence wavelength at half maximum) of ytterbium phosphate glasses are increased.
Funding Organization国家自然科学基金(69988006) ; 国家自然科学基金(69988006) ; 上海市光科技项目(022261046) ; 上海市光科技项目(022261046) ; 国家自然科学基金(69988006) ; 国家自然科学基金(69988006) ; 上海市光科技项目(022261046) ; 上海市光科技项目(022261046)
Indexed BySCI
Language中文
Funding Organization国家自然科学基金(69988006) ; 国家自然科学基金(69988006) ; 上海市光科技项目(022261046) ; 上海市光科技项目(022261046) ; 国家自然科学基金(69988006) ; 国家自然科学基金(69988006) ; 上海市光科技项目(022261046) ; 上海市光科技项目(022261046)
WOS IDWOS:000183216200005
Citation statistics
Document Type期刊论文
Version出版稿
Identifierhttp://ir.siom.ac.cn/handle/181231/18348
Collection高功率激光单元技术研发中心
Corresponding AuthorDai, SX (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
Affiliation1.Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
2.S China Univ Technol, Mat Res Lab Opt & Commun, Guangzhou 510641, Peoples R China
Recommended Citation
GB/T 7714
戴世勋,杨建虎,戴能利,等. MF2(M=Mg,Ca,Zn,Sr,Ba)对掺Yb^3+磷酸盐玻璃性质的影响[J]. 无机材料学报,2003,18(3):540.
APA 戴世勋,杨建虎,戴能利,胡丽丽,姜中宏,&Dai, SX .(2003).MF2(M=Mg,Ca,Zn,Sr,Ba)对掺Yb^3+磷酸盐玻璃性质的影响.无机材料学报,18(3),540.
MLA 戴世勋,et al."MF2(M=Mg,Ca,Zn,Sr,Ba)对掺Yb^3+磷酸盐玻璃性质的影响".无机材料学报 18.3(2003):540.
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