含ZrF4氟铝酸盐玻璃研究 | |
Alternative Title | Investigation on fluoroaluminate glasses containing ZrF4 |
曹国喜; 范有余; 胡和方; 干福熹; Cao, GX (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China | |
2003 | |
Source Publication | 无机材料学报
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Volume | 18Issue:3Pages:533 |
Abstract | 以10MgF2-20CaF2-10SrF2-10BaF2-15YF3-35A1F3(摩尔百分数)氟铝酸盐玻璃为基本组成,在玻璃中引入不同含量的ZrF4,同时对其它组成进行适当调整,制得了厚度8mm无可见析晶的氟化物玻璃.利用差热分析(DTA)技术研究了ZrF4对玻璃形成能力和玻璃析晶动力学的影响,结果表明,少量的ZrF4可以提高玻璃的抗失透能力,过量的ZrF4会降低玻璃形成能力;ZrF4的最佳含量范围为7.3-11.4mol%.根据测得的玻璃的红外透过光谱显示,该玻璃具有良好的透红外光性能. |
Subtype | Article |
Other Abstract | Varying contents of ZrF4 were incorporated into the fluoroaluminate base-glass having a composition of 10MgF(2)- 20CaF(2)-10SrF(2)-BaF2-15YF(3)-36AlF(3) (molar percent), contents of other components being adjusted properly, fluoride glasses having no visible crystallization were obtained, these glasses can reach to 8mm thick. The content influences of ZrF4 on the ability to form glass and kinetics of crystallization were investigated by differential thermal analysis (DTA) technique. The results indicate that a small amount of ZrF4 will improve the anti-devitrification ability of glasses, but too much ZrF4 maybe depress the ability to form glass. The best content range of ZrF4 is from 7.3% to 11.4%. Moreover, the measured infrared transmitting spectra prove that these glasses have good optical property of infrared transmitting. |
Funding Organization | 国防科工委项目 ; 国防科工委项目 ; 国防科工委项目 ; 国防科工委项目 |
Indexed By | SCI |
Language | 中文 |
Funding Organization | 国防科工委项目 ; 国防科工委项目 ; 国防科工委项目 ; 国防科工委项目 |
WOS ID | WOS:000183216200004 |
Citation statistics | |
Document Type | 期刊论文 |
Version | 出版稿 |
Identifier | http://ir.siom.ac.cn/handle/181231/18347 |
Collection | 高功率激光单元技术研发中心 |
Corresponding Author | Cao, GX (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China |
Affiliation | Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China |
Recommended Citation GB/T 7714 | 曹国喜,范有余,胡和方,等. 含ZrF4氟铝酸盐玻璃研究[J]. 无机材料学报,2003,18(3):533. |
APA | 曹国喜,范有余,胡和方,干福熹,&Cao, GX .(2003).含ZrF4氟铝酸盐玻璃研究.无机材料学报,18(3),533. |
MLA | 曹国喜,et al."含ZrF4氟铝酸盐玻璃研究".无机材料学报 18.3(2003):533. |
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357.pdf(420KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text |
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