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含ZrF4氟铝酸盐玻璃研究
Alternative TitleInvestigation on fluoroaluminate glasses containing ZrF4
曹国喜; 范有余; 胡和方; 干福熹; Cao, GX (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
2003
Source Publication无机材料学报
Volume18Issue:3Pages:533
Abstract以10MgF2-20CaF2-10SrF2-10BaF2-15YF3-35A1F3(摩尔百分数)氟铝酸盐玻璃为基本组成,在玻璃中引入不同含量的ZrF4,同时对其它组成进行适当调整,制得了厚度8mm无可见析晶的氟化物玻璃.利用差热分析(DTA)技术研究了ZrF4对玻璃形成能力和玻璃析晶动力学的影响,结果表明,少量的ZrF4可以提高玻璃的抗失透能力,过量的ZrF4会降低玻璃形成能力;ZrF4的最佳含量范围为7.3-11.4mol%.根据测得的玻璃的红外透过光谱显示,该玻璃具有良好的透红外光性能.
SubtypeArticle
Other AbstractVarying contents of ZrF4 were incorporated into the fluoroaluminate base-glass having a composition of 10MgF(2)- 20CaF(2)-10SrF(2)-BaF2-15YF(3)-36AlF(3) (molar percent), contents of other components being adjusted properly, fluoride glasses having no visible crystallization were obtained, these glasses can reach to 8mm thick. The content influences of ZrF4 on the ability to form glass and kinetics of crystallization were investigated by differential thermal analysis (DTA) technique. The results indicate that a small amount of ZrF4 will improve the anti-devitrification ability of glasses, but too much ZrF4 maybe depress the ability to form glass. The best content range of ZrF4 is from 7.3% to 11.4%. Moreover, the measured infrared transmitting spectra prove that these glasses have good optical property of infrared transmitting.
Funding Organization国防科工委项目 ; 国防科工委项目 ; 国防科工委项目 ; 国防科工委项目
Indexed BySCI
Language中文
Funding Organization国防科工委项目 ; 国防科工委项目 ; 国防科工委项目 ; 国防科工委项目
WOS IDWOS:000183216200004
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Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.siom.ac.cn/handle/181231/18347
Collection高功率激光单元技术研发中心
Corresponding AuthorCao, GX (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
AffiliationChinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
Recommended Citation
GB/T 7714
曹国喜,范有余,胡和方,等. 含ZrF4氟铝酸盐玻璃研究[J]. 无机材料学报,2003,18(3):533.
APA 曹国喜,范有余,胡和方,干福熹,&Cao, GX .(2003).含ZrF4氟铝酸盐玻璃研究.无机材料学报,18(3),533.
MLA 曹国喜,et al."含ZrF4氟铝酸盐玻璃研究".无机材料学报 18.3(2003):533.
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