| 掺Er~(3+)铋酸盐玻璃的荧光光谱分析 | |
| Alternative Title | Fluorescence spectrum analysis of erbium-doped bismuth-based glass |
| 杨建虎; 戴世勋; 戴能利; 温磊; 胡丽丽; 姜中宏; Yang, JH (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China | |
| 2003 | |
| Source Publication | 光谱学与光谱分析
 |
| Volume | 23Issue:6Pages:1065 |
| Abstract | 研究了Er~(3+)离子在铋酸盐玻璃中的荧光光谱性质，应用Juddl-Ofelt理论计算了铋酸盐玻璃中Er~(3+)离子的强度参数Omega_t(t=2, 4, 6)及~4I_(13/2)~4I_(15/2)跃迁的谱线强度比值S_(ed)/(S_(ed)+S_(md))，给出了铋酸盐玻璃中Er~(3+)离子具有宽带发射的结构性解释，表明了Er~(3+)离子晶体场强度与S_(ed)/(S_(ed)+S_(md))间存在的反比关系。 |
| Subtype | Article |
| Other Abstract | The fluorescence spectra of Er3+ in bismuth-based glass were analyzed in this work. From the structural properties the strength parameters, Omega(t) ( t = 2, 4, 6), and line strengths of I-4(13/2)--> I-4(15/2) transition of Er3+ were calculated according to the Judd-Ofelt theory. The results show that Er-O bond has much weaker covalency in bismuth-based glass than that in other glass hosts. With the increase of B2O3 content, the covalency of Er-O bond becomes weaker, the Omega(6) parameter and S-ed / (S-ed + S-md) ratio increase monotonously, the crystal field strength around Er3+ ion sites becomes weaker, the variation in crystal field around Er3+ ion from site to site becomes greater which leads to a more inhomogeneous distribution of Er3+ sites, then leading to a more inhomogeneous broadening of the spectra, and the FWHM parameter of I-4(13/2) --> I-4(15/2) transition of Er3+ ion becomes broader accordingly. Furthermore, a relationship between the crystal field around Er3+ sites and the line strength of I-4(13/2)--> I-4(15/2) transition of Er3+ ion was found that the former is inversely proportional to the latter, which gives ways for researchers to evaluate the crystal field strength around Er3+ site more easily. |
| Funding Organization | 国家自然科学基金（60207006） ; 国家自然科学基金（60207006） ; 上海市光科技项目（022261046）资助项目 ; 上海市光科技项目（022261046）资助项目 ; 国家自然科学基金（60207006） ; 国家自然科学基金（60207006） ; 上海市光科技项目（022261046）资助项目 ; 上海市光科技项目（022261046）资助项目 |
| Indexed By | SCI |
| Language | 中文 |
| Funding Organization | 国家自然科学基金（60207006） ; 国家自然科学基金（60207006） ; 上海市光科技项目（022261046）资助项目 ; 上海市光科技项目（022261046）资助项目 ; 国家自然科学基金（60207006） ; 国家自然科学基金（60207006） ; 上海市光科技项目（022261046）资助项目 ; 上海市光科技项目（022261046）资助项目 |
| WOS ID | WOS:000187863200008 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Version | 出版稿 |
| Identifier | http://ir.siom.ac.cn/handle/181231/18201 |
| Collection | 高功率激光单元技术研发中心 |
| Corresponding Author | Yang, JH (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China |
| Affiliation | Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China |
| Recommended Citation GB/T 7714 | 杨建虎,戴世勋,戴能利,等. 掺Er~(3+)铋酸盐玻璃的荧光光谱分析[J]. 光谱学与光谱分析,2003,23(6):1065. |
| APA | 杨建虎.,戴世勋.,戴能利.,温磊.,胡丽丽.,...&Yang, JH .(2003).掺Er~(3+)铋酸盐玻璃的荧光光谱分析.光谱学与光谱分析,23(6),1065. |
| MLA | 杨建虎,et al."掺Er~(3+)铋酸盐玻璃的荧光光谱分析".光谱学与光谱分析 23.6(2003):1065. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 214.pdf（139KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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