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题名:
Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics
作者: Hanlon, Damien; Backes, Claudia; Doherty, Evie; Cucinotta, Clotilde S.; Berner, Nina C.; Boland, Conor; Lee, Kangho; Harvey, Andrew; Lynch, Peter; Gholamvand, Zahra; Zhang, Saifeng; Wang, Kangpeng; Moynihan, Glenn; Pokle, Anuj; Ramasse, Quentin M.; McEvoy
通讯作者: Coleman, JN (reprint author), Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland.
刊名: Nat. Commun.
发表日期: 2015
DOI: 10.1038/ncomms9563
卷: 6, 页:8563
文章类型: Article
收录类别: SCI
英文摘要: Few-layer black phosphorus (BP) is a new two-dimensional material which is of great interest for applications, mainly in electronics. However, its lack of environmental stability severely limits its synthesis and processing. Here we demonstrate that high-quality, few-layer BP nanosheets, with controllable size and observable photoluminescence, can be produced in large quantities by liquid phase exfoliation under ambient conditions in solvents such as N-cyclohexyl-2-pyrrolidone (CHP). Nanosheets are surprisingly stable in CHP, probably due to the solvation shell protecting the nanosheets from reacting with water or oxygen. Experiments, supported by simulations, show reactions to occur only at the nanosheet edge, with the rate and extent of the reaction dependent on the water/oxygen content. We demonstrate that liquid-exfoliated BP nanosheets are potentially useful in a range of applications from ultrafast saturable absorbers to gas sensors to fillers for composite reinforcement.
语种: 英语
项目资助者: European Union Seventh Framework Programme [604391] ; Science Foundation Ireland (SFI) [SFI/12/RC/2278] ; European Research Council (SEMANTICS) ; SFI [11/PI/1087, PI_10/IN.1/I3030] ; German research foundation DFG [BA 4856/1-1] ; SFI Investigator Award [12/IA/1306] ; External Cooperation Program of BIC, CAS [181231KYSB20130007] ; European Research Council (Quest project) ; Science Foundation Ireland ; EU [FP7/2013-IEF-627386] ; [HPC_12_0722] ; [HPC_14_00800]
Citation statistics:
内容类型: 期刊论文
版本: 出版稿
URI标识: http://ir.siom.ac.cn/handle/181231/14263
Appears in Collections:中科院强激光材料重点实验室_期刊论文

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作者单位: 1.[Hanlon, Damien
2.Backes, Claudia
3.Doherty, Evie
4.Cucinotta, Clotilde S.
5.Berner, Nina C.
6.Boland, Conor
7.Lee, Kangho
8.Harvey, Andrew
9.Lynch, Peter
10.Gholamvand, Zahra
11.Wang, Kangpeng
12.Moynihan, Glenn
13.Pokle, Anuj
14.McEvoy, Niall
15.Blau, Werner J.
16.Sanvito, Stefano
17.O'Regan, David D.
18.Duesberg, Georg S.
19.Nicolosi, Valeria
20.Coleman, Jonathan N.] Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland
21.[Hanlon, Damien
22.Backes, Claudia
23.Doherty, Evie
24.Cucinotta, Clotilde S.
25.Boland, Conor
26.Harvey, Andrew
27.Lynch, Peter
28.Gholamvand, Zahra
29.Wang, Kangpeng
30.Moynihan, Glenn
31.Pokle, Anuj
32.Blau, Werner J.
33.Sanvito, Stefano
34.O'Regan, David D.
35.Nicolosi, Valeria
36.Coleman, Jonathan N.] Trinity Coll Dublin, CRANN Res Ctr, Dublin 2, Ireland
37.[Hanlon, Damien
38.Backes, Claudia
39.Doherty, Evie
40.Cucinotta, Clotilde S.
41.Boland, Conor
42.Harvey, Andrew
43.Lynch, Peter
44.Gholamvand, Zahra
45.Wang, Kangpeng
46.Moynihan, Glenn
47.Pokle, Anuj
48.Blau, Werner J.
49.Sanvito, Stefano
50.O'Regan, David D.
51.Nicolosi, Valeria
52.Coleman, Jonathan N.] Trinity Coll Dublin, AMBER Res Ctr, Dublin 2, Ireland
53.[Doherty, Evie
54.Berner, Nina C.
55.Lee, Kangho
56.Pokle, Anuj
57.McEvoy, Niall
58.Duesberg, Georg S.
59.Nicolosi, Valeria] Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland
60.[Zhang, Saifeng
61.Wang, Kangpeng
62.Wang, Jun] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China
63.[Ramasse, Quentin M.] STFC Daresbury Campus, SuperSTEM Lab, Warrington WA4 4AD, Cheshire, England
64.[Abellan, Gonzalo
65.Hauke, Frank
66.Hirsch, Andreas] Univ Erlangen Nurnberg, Chair Organ Chem 2, D-91054 Erlangen, Germany
67.[Abellan, Gonzalo
68.Hauke, Frank
69.Hirsch, Andreas] Univ Erlangen Nurnberg, Inst Adv Mat & Proc ZMP, D-91054 Erlangen, Germany

Recommended Citation:
Hanlon, Damien,Backes, Claudia,Doherty, Evie,et al. Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics[J]. Nat. Commun.,2015,6:8563.
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